Palladium-Catalyzed 2-(Neopentylsulfinyl)aniline Directed C-H Acetoxylation and Alkenylation of the Arylacetamides

Maryia V. Barysevich,Marharyta V. Laktsevich-Iskryk,Anastasiya V. Krech,Vladimir N. Zhabinskii,Vladimir A. Khripach,Alaksiej L. Hurski

Palladium-Catalyzed 2-(Neopentylsulfinyl)aniline Directed C-H Acetoxylation and Alkenylation of the Arylacetamides

2019

Maryia V. Barysevich
Marharyta V. Laktsevich-Iskryk
Anastasiya V. Krech
Vladimir N. Zhabinskii
Vladimir A. Khripach
Alaksiej L. Hurski

A directing group that promotes very fast diacetoxylation of the arylacetamides is reported. The auxiliary also promotes alkenylation with vinyl ketones, which were generated in one-pot from the cyclopropanols.

Keywords:

Aniline
Chemistry
Cyclopropanol
Catalysis
Palladium
Medicinal chemistry

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