Les équilibres solide–liquide dans des systèmes binaires formiate d'alcalin-formiate d'alcalino-terreux

The liquid–solid equilibrium temperatures of the (HCOOMe)2 + (HCOO)2Me′ (where Me = Na, K, Tl; Me′ = Mg, Ca, Sr, Ba) binary systems were determined. The deviations from the ideal curve T = ΔHfus/(ΔSfus − R ln x) are explained by the polarization effect of the ions.