Assembly and Dynamic Analysis of Square ColloidalCrystals via Templated Capillary Assembly
2019
Capillary assembly has the ability to engineer centimeter-sized regions of discrete colloidal superstructures and microarrays. However, its use as a tool for directing crystallization of colloids into surface-bound nonclose-packed arrays is limited. Furthermore, the use of quantitative particle tracking tools to investigate evaporative assembly dynamics is rarely employed. In this contribution, we use templated capillary assembly to fabricate square-packed lattices of spherical, organosilica colloids using designed patterned boundaries. Particle tracking algorithms reveal that the assembly of square-packed regions is controlled by the interplay between confinement-driven nuclei formation and osmotic pressure-driven restructuring. We find that the incorporation of a square template increases the yield of particles bearing four nearest neighbors (Zn = 4) from 4 to 39%, obtained using a heavier and more viscous solvent. Maximal square-packed domains occur at specific initial particle concentrations (1.75–2.2...
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