Perspective for Uranyl Photo-Redox Catalysis

The application of uranyl salts as powerful photoredox catalysts in chemical transformations lags behind the advances achieved in thermocatalysis and structural chemistry. In fact, uranyl cations (UO2 2+) have proven to be ideal photoredox catalysts in visible-light-driven chemical reactions. The excited state of uranyl cations (*UO2 2+) that is generated by visible-light irradiation has a long-lived fluorescence lifetime up to microseconds and high oxidizing ability [E o = +2.6 V vs. standard hydrogen electrode (SHE)]. After ligand-to-metal charge transfer (LMCT), quenching occurs with organic substrates via hydrogen-atom transfer (HAT) or single-electron transfer (SET). Interestingly, the ground state and excited state of uranyl cations (UO2 2+) are chemically inert toward oxygen molecules, preventing undesired transformations from active oxygen species. This review summarizes recent advances in photoredox transformations enabled by uranyl salts. 1 Introduction 2 The Application of Uranyl Photoredox Catalysis in HAT Mode 3 The Application of Uranyl Photoredox Catalysis in SET Mode 4 Conclusion and Outlook