Controlling Coordination Number of Rhodium(III) Complex by Ligand-based Redox for Catalytic C–H Amination

The rhodium (III) complexes supported by a di-deprotonated o-phenylenediamido ligand, ([Cp*RhIII(C6H4N2tBu2Ph22–)] ([Cp*RhIII(L2–)], 1), and its one-electron and two-electron oxidized ligands, [Cp*...