Soil Permittivity Response to Bulk Electrical Conductivity for Selected Soil Water Sensors

2013 
Bulk electrical conductivity (σ a ) can dominate the low frequency dielectric loss spectrum in soils, causing changes in the permittivity and errors in estimated water content. We examined the dependence of measured apparent permittivity ( K a ) on σ a in contrasting soils using time-domain reflectometry (TDR), a digital time-domain transmission (TDT) sensor, and a capacitance sensor (5TE) during near saturated solute displacement experiments. Sensors were installed in columns packed with fine sand or a clay loam soil. Displacement experiments were completed by first equilibrating columns with 0.25 dS m −1 CaCl 2 , introducing a step pulse of ∼4.7 dS m −1 CaCl 2 and, after equilibration, displacing the resident solution with 0.25 dS m −1 CaCl 2 . Using TDR, measured K a increased with increasing σ a ; however, the slope of this response averaged 3.47 m dS1 for clay loam compared with 0.19 m dS1 for sand. The large response in the clay loam was attributed to relaxation losses that narrowed the effective bandwidth from 821 to an estimated 164 MHz. In contrast, the effective frequency in sand averaged 515 MHz. Permittivity measured using the TDT probe exhibited little or no sensitivity to σ a ( −1 ) in both media. Measured K a using the 5TE probe declined with increasing σ a up to 1 to 1.8 dS m −1 and then increased thereafter with net negative responses for sand (Δ K a /Δσ a = −3.1 m dS1 ) and net positive responses for the clay loam (Δ K a /Δσ a = 2.9 m dS1 ). Consideration of the K a –σ a response is required for accurate soil water content estimation (±0.03 m 3 m −3 ) in the presence of solution EC variations using TDR in fine-textured soils or the 5TE sensor in all media. Large differences in the sampling volumes between 5TE-measured bulk EC and permittivity confounded the K a –σ a response in the presence of a concentration gradient.
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