Synthesis and photoluminescence properties of the high-brightness Eu3+-doped Sr3Y(PO4)3 red phosphors

Abstract A series of red-emitting phosphors Eu 3+ -doped Sr 3 Y(PO 4 ) 3 have been successfully synthesized by conventional solid-state reaction, and its photoluminescence properties have been investigated. The excitation spectra reveal strong excitation bands at 392 nm, which match well with the popular emissions from near-UV light-emitting diode chips. The emission spectra of Sr 3 Y(PO 4 ) 3 :Eu 3+ phosphors exhibit peaks associated with the 5 D 0  →  7 F J ( J  = 0, 1, 2, 3, 4) transitions of Eu 3+ and have dominating emission peak at 612 nm under 392 nm excitation. The integral intensity of the emission spectra of Sr 3 Y 0.94 (PO 4 ) 3 :0.06Eu 3+ phosphors excited at 392 nm is about 3.4 times higher than that of Y 2 O 3 :Eu 3+ commercial red phosphor. The Commission Internationale de l’Eclairage chromaticity coordinates, the quantum efficiencies and decay times of the phosphors excited under 392 nm are also investigated. The experimental results indicate that the Eu 3+ -doped Sr 3 Y(PO 4 ) 3 phosphors are promising red-emitting phosphors pumped by near-UV light.