Direct Access to Highly Enantioenriched α-Branched Acrylonitriles through a One-Pot Sequential Asymmetric Michael Addition/Retro-Dieckmann/Retro-Michael Fragmentation Cascade

Nicolas Duchemin,Martin Cattoen,Oscar Gayraud,Silvia Anselmi,Bilal Siddiq,Roberto Buccafusca,Marc Daumas,Vincent Ferey,Michael Smietana,Stellios Arseniyadis

Direct Access to Highly Enantioenriched α-Branched Acrylonitriles through a One-Pot Sequential Asymmetric Michael Addition/Retro-Dieckmann/Retro-Michael Fragmentation Cascade

2020

Nicolas Duchemin
Martin Cattoen
Oscar Gayraud
Silvia Anselmi
Bilal Siddiq
Roberto Buccafusca
Marc Daumas
Vincent Ferey
Michael Smietana
Stellios Arseniyadis

A highly enantioselective synthesis of α-branched acrylonitriles is reported featuring a one-pot sequential asymmetric Michael addition/retro-Dieckmann/retro-Michael fragmentation cascade. The meth...

Keywords:

Cascade
Fragmentation (computing)
Chemistry
Enantioselective synthesis
Organic chemistry
Michael reaction

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