Controlled‐Atmosphere Flame Fusion Single Crystal Growth of non‐noble fcc, hcp and bcc metals using Copper, Cobalt and Iron

The growth of noble metal single crystals via the flame fusion method was developed in the 1980's. Since then, there has been no major advancements to the technique until the recent development of the controlled-atmosphere flame fusion (CAFF) method to grow non-noble, Ni single crystals. Herein, we demonstrate the generality of this method with the first preparation of fcc Cu as well as the first hcp and bcc single crystals of Co and Fe, respectively. The high quality of the single crystals was verified using scanning electron microscopy and Laue X-ray backscattering. Based on Wulff constructions the equilibrium shapes of the single crystal particles were studied, confirming the symmetry of the fcc, hcpand bcc single crystal lattices. The low cost of the CAFF method makes all kinds of high quality non-noble single crystals independent of its lattice accessible for use in electrocatalysis, electrochemistry, surface science and materials science.