Optimizing polymer electrolyte membrane thickness to maximize fuel cell vehicle range

Abstract Automotive hydrogen polymer electrolyte membrane (PEM) fuel cell systems require periodic purges to remove nitrogen and water from the anode. Purging increases system performance by limiting anode hydrogen dilution, but reduces hydrogen utilization. State of the art fuel cell membrane electrode assemblies utilize thin ionomer membranes in an effort to increase performance and reduce cost. Thinner membranes also increase the required anode purge rates due to the increased transport of inert gases. A model was developed to examine the relationship between membrane thickness and vehicle range which takes into account anode purge rate. The model includes changes in efficiency and hydrogen utilization as a function of PEM thickness for a variety of operating conditions. The model predicts that an optimal membrane thickness which maximizes vehicle range exists, but this thickness is highly dependent on other system conditions. The results of this study can be extended to help optimize stack development and balance of plant design.