Remarkable viscoelasticity in mixtures of cyclodextrins and nonionic surfactants

We report the effect of native cyclodextrins (α, β, and γ) and selected derivatives in modulating the self-assembly of the nonionic surfactant polyoxyethylene cholesteryl ether (ChEO10) and its mixtures with triethylene glycol monododecyl ether (C12EO3), which form wormlike micelles. Cyclodextrins (CDs) generally induce micellar breakup through a host–guest interaction with surfactants; instead, we show that a constructive effect, leading to gel formation, is obtained with specific CDs and that the widely invoked host–guest interaction may not be the only key to the association. When added to wormlike micelles of ChEO10 and C12EO3, native β-CD, 2-hydroxyethyl-β-CD (HEBCD), and a sulfated sodium salt of β-CD (SULFBCD) induce a substantial increase of the viscoelasticity, while methylated CDs rupture the micelles, leading to a loss of the viscosity, and the other CDs studied (native α- and γ- and hydroxypropylated CDs) show a weak interaction. Most remarkably, the addition of HEBCD or SULFBCD to pure ChEO10...