Rhoda‐Electrocatalyzed Bimetallic C–H Oxygenation by Weak O‐Coordination
2021
Rhodium-electrocatalyzed arene C-H oxygenation by weakly O- coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C-H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C-H activation by a bimetallic rhodium catalysis manifold.
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