Fluorescent non-linear chiral polymer chemosensor bonded alternatively with 1,4-diethynyl-2,5-dioctyloxybenzene and (R,R)-salen for Zn2+recognition

Abstract Stereoregular non-linear chiral main chain polymers 1a – b bonded alternatively with ( R , R )-salen and 1,4-diethynyl-2,5-dioctyloxybenzene moieties have been synthesized using palladium catalyzed C–C cross-coupling and Schiff base formation reactions as the key steps. These polymers are soluble in common organic solvents, and act as an effective chemosensor for the detection of Zn 2+ with respect to other metal ions with enhanced fluorescence. The CD spectra observed for the polymers 1a – b could be attributed to the helical secondary structure with a low degree of inter-strand interactions. This reduced inter-strand interaction has been ascertained from the titration of pyridine to the Zn(II)-polymer 1b complex, which results in minor changes in the fluorescence emission.