Synthesis and electrochemical performance of bud-like FeS2 microspheres as anode materials for rechargeable lithium batteries
2013
Abstract Bud-like FeS 2 powder was synthesized by a solvothermal method with the help of polyvinylpyrrolidone (PVP). The bud-like FeS 2 microshperes with the diameters of 2.0–3.0 μm were consisted of the submicro-flakes with 0.5–1μm in width and length, and about 60 nm in thickness. As an anode material for Li-ion batteries, the bud-like FeS 2 delivered initial specific discharge capacity of 773 and 749 mAh g −1 , and could sustain 387 and 368 mAh g −1 after 30 cycles at current densities of 45 and 89 mA g −1 , respectively, much higher than the solid one obtained without PVP. The bud-like FeS 2 microshperes also showed large diffusion coefficient of Li-ions ( D Li + ) calculated by Galvanostatic intermittent titration (GITT). The improved electrochemical performance of bud-like FeS 2 was due to the unique structure which provides large contact area between the FeS 2 microspheres and electrolyte, decreased polarization and large D Li + , leading to enhanced electrode reaction kinetics.
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