Characterization of Nb Interface Segregation During Welding Thermal Cycle in Microalloyed Steel by Atom Probe Tomography

Coarse-grained, welding heat-affected zone microstructure was simulated in a Nb-bearing microalloyed steel. The granular bainite with a great number of martensite-austenite (M-A) constituents was the predominant phase. Using atom probe tomography (APT), the distributions of niobium at prior austenite grain boundary (PAGB), ferrite/martensite-austenite (M-A) constituent interface (FMAI), and ferrite/ferrite interface (FFI) were investigated. The binding energy of Nb atom and vacancy was predicted to be 0.45 eV, indicating that Nb segregation by welding thermal cycle is probably a result of the nonequilibrium mechanism. The maximum enrichment of Nb was found at FMAI with enrichment factor of 3.50. Intermediate enrichment of Nb was at PAGB with enrichment factor of 3.12. The interfacial excess of Nb solute element ГNb at PAGB determined by APT was 0.27 × 1019 atoms/m2. The segregation energy was calculated to be 22.91 kJ/mol. The minimum enrichment of Nb was at FFI with an enrichment factor of 1.80.