Synthesis of indolo[3,2-b]carbazole-based random copolymers for polymer solar cell applications
2013
Abstract In addition to preparing two indolocarbazole-based random copolymers (named as r -PICTBT1 and r -PICTBT2), this work investigated their feasibility for bulk heterojunction polymer solar cells (PSCs). These copolymers consisted of commercially available 3,9-dibromo-5,11-dioctyl-5,11-dihydroindole[3,2- b ]carbazole, 2,5-bis(trimethylstannyl) thiophene and dibromobenzo[ c ][1,2,5]thiadiazole by varying the feed in ratios via Stille cross-coupling reactions. The photophysical and electrochemical properties of the resulting copolymers could be fine-modulated easily by adjusting the feed ratios of monomers. Both copolymers in the thin film state exhibited two obvious peaks and a vibronic shoulder in the absorption spectra. Electrochemical experiments indicated that the highest occupied molecular orbital energy levels were − 4.95, − 5.00 eV; meanwhile, the lowest unoccupied molecular orbital energy levels were − 3.38, − 3.54 eV for r -PICTBT1 and r -PICTBT2, respectively. Bulk heterojunction PSCs composed of an electron-donor copolymer blended with an electron acceptor [6] , [6] -phenyl-C61-butyric acid methyl ester (PC 61 BM) or [6] , [6] -phenyl-C71-butyric acid methyl ester (PC 71 BM) at a weight ratio of 1:1 or 1:3 were investigated. Moreover, the r -PICTBT2/PC 71 BM-based (w/w = 1:1) PSC performed the best with an open-circuit voltage of 0.54 V, short-circuit current of 6.83 mA/cm 2 , fill factor of 0.44, and power conversion efficiency of 1.63%.
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