“Ether-Linked” Organometallic Catalysts for Ketone Reduction Reactions
2007
The synthesis and applications to asymmetric ketone hydrogenation of a series of novel Ru(II) catalysts is described. The design of the ligands ensures that the configuration at the metal atom is retained and cannot invert during the catalytic cycle. The catalysts generate alcohols in moderate to good enantiomeric excess and conversion.
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