Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes
2004
Abstract Trimethylaluminium induces a stereoselective rearrangement of unsaturated glycosides into polyfunctionalised cyclohexanic rings containing a tertiary alcohol and retaining the anomeric group. In contrast with the previously used triisobutylaluminium, no de- O -benzylation reaction was observed.
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