Synthesis of soluble polymers from dimethacrylate compounds

The possibility of obtaining soluble (co) polymers on polymerization of α,ω-dimethacrylates in dilute solutions with radiation and “material” modes of initiation is shown. In the polymer based on TGM-3 free double bonds are absent. From the data of viscometry light scatter and GPC the authors evaluate the magnitudes of the statistical Kuhn segment and the parameter of braking of the internal rotation of the soluble TGM-3 polymer. The totality of the experimental factors is due to the cyclolinear structure of the soluble polymer containing one to two long chain branches per macromolecule.