Binding selectivity and separation of p-functionalized toluenes with a metallo-cavitand in water.
2020
Metallo cavitand (1-2Pd) showed unprecedented binding selectivity and sequestration of p-functionalized toluene isomers in water. The host-guest complexation was studied by 1H and COSY NMR methods and xylene-isomer complexes were examined by DFT calculations. A liquid-liquid extraction scheme was developed for separation of p-functionalized toluenes.
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