Preparation, X-ray molecular structure determination, and chemical properties of dinitrogen-coordinated cobalt complexes containing triphenylphosphine ligands and alkali metal or magnesium: protonation of the coordinated dinitrogen to ammonia and hydrazine

Akio Yamamoto,Yoshikiyo Miura,Takashi Ito,Hui-Lin Chen,Kiyoshi Iri,Fumiyuki Ozawa,Kunio Miki,Tsuyoshi Sei,Nobuo Tanaka,Nobutami Kasai

Preparation, X-ray molecular structure determination, and chemical properties of dinitrogen-coordinated cobalt complexes containing triphenylphosphine ligands and alkali metal or magnesium: protonation of the coordinated dinitrogen to ammonia and hydrazine

1983

Akio Yamamoto
Yoshikiyo Miura
Takashi Ito
Hui-Lin Chen
Kiyoshi Iri
Fumiyuki Ozawa
Kunio Miki
Tsuyoshi Sei
Nobuo Tanaka
Nobutami Kasai

Preparation de [Co(N 2 )(PPh 3 ) 3 ] 2 Mg(THF) 4 (2) [Co(N 2 )(PPh 3 ) 3 ] Li(Et 2 O) 3 (3) et [Co(N 2 ) (PPh 3 ) 3 ] Li(THF) 3 (4). On prepare egalement [Co(N 2 ) (PPh 3 ) 3 ] N-(THF) (5). Etude RX de (3) et (4)

Keywords:

Triphenylphosphine
Protonation
Alkali metal
Photochemistry
Molecule
Inorganic chemistry
Magnesium
Ammonia
Cobalt
Ligand
Chemistry

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