Direct reductive alkylation of amine hydrochlorides with aldehyde bisulfite adducts

Marta Barniol-Xicota,Andreea L. Turcu,Sandra Codony,Carmen Escolano,Santiago Vázquez

Direct reductive alkylation of amine hydrochlorides with aldehyde bisulfite adducts

2014

Marta Barniol-Xicota
Andreea L. Turcu
Sandra Codony
Carmen Escolano
Santiago Vázquez

Abstract A mild procedure for the direct reaction of aromatic and aliphatic aldehyde bisulfite adducts with primary and secondary amine hydrochlorides in the presence of sodium cyanoborohydride in methanol is reported.

Keywords:

Adduct
Methanol
Aldehyde
Alkylation
Sodium cyanoborohydride
Photochemistry
Organic chemistry
Bisulfite
Reductive amination
Chemistry
Inorganic chemistry
Amine gas treating
Sodium bisulfite

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