High dispersion of 1-nm SnO2 particles between graphene nanosheets constructed using supercritical CO2 fluid for sodium-ion battery anodes
2016
Abstract Supercritical CO 2 (SCCO 2 ) fluid, which has gas-like diffusivity, extremely low viscosity, and near-zero surface tension, is used to synthesize SnO 2 nanoparticles (a 1-nm diameter is achievable), which are uniformly dispersed and tightly anchored on graphene nanosheets (GNSs) and carbon nanotubes (CNTs). The discharge capacity, rate capability, and cyclic stability of the synthesized SnO 2 /GNS and SnO 2 /CNT nanocomposites are compared. This study also tunes the SCCO 2 temperature (and thus its fluid density) and finds that this factor crucially affects the SnO 2 size and distribution, determining the resulting electrochemical properties. The sodiation/desodiation mechanism of the SnO 2 /GNS electrode is examined using synchrotron ex situ X-ray absorption and X-ray diffraction techniques, together with transmission electron microscopy. We confirm that while the oxide conversion reaction is reversible, the sluggish Sn–Na alloying/dealloying reaction is responsible for the lower measured capacity as compared to the theoretical value. The first-cycle efficiency loss is mainly attributed to the trapping of Na in the electrode surface solid electrolyte interphase layer.
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