Poly(N-vinylcarbazole) as an advanced organic cathode for potassium-ion-based dual-ion battery
2019
Abstract Owing to the unique redox reaction and the relative low molar mass of the repeating unit, poly(N-vinylcarbazole) (PVK) was selected as an advanced organic cathode for potassium-ion-based dual-ion battery (PDIB) with the K foil anode and KPF 6 -based electrolyte. The operation mechanism of this PDIB is that PF 6 − anions are migrated from the electrolyte and incorporated into PVK cathode via the attraction to the positively charged N atom of carbazole ligand, and then are released into the electrolyte in the subsequent discharge process; simultaneously, K + cations are reversibly stored/removed in/from the anode during charging/discharging. It shows a high median operation potential of 4.05 V vs. K + /K and can achieve a high specific capacity of 117 mAh g −1 at 20 mA g −1 , which is close to its theoretical value of 138 mAh g −1 . More impressively, even at the highest current density of 2000 mA g −1 for 500 cycles, a high average specific capacity of 61 mAh g −1 can still be obtained with capacity rentation of 55%.
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