Evaluation of the Relationship between the Catalyst Structure and Regio- as well as Stereoselectivity in the Chiral Ammonium Bifluoride-Catalyzed Asymmetric Addition of Silyl Nitronates to α, β-Unsaturated Aldehydes

Takashi Ooi,K. Morimoto,Kanae Doda,Keiji Maruoka

Evaluation of the Relationship between the Catalyst Structure and Regio- as well as Stereoselectivity in the Chiral Ammonium Bifluoride-Catalyzed Asymmetric Addition of Silyl Nitronates to α, β-Unsaturated Aldehydes

2004

Takashi Ooi
K. Morimoto
Kanae Doda
Keiji Maruoka

Unique relationship between the catalyst structure and regio-and stereoselectivity in the chiral quaternary ammonium bifluoride-catalyzed asymmetric addition of silyl nitronates to α,β-unsaturated aldehydes has been reported.

Keywords:

Addition reaction
Ammonium bifluoride
Catalysis
Silylation
Ammonium
Chirality (chemistry)
Organic chemistry
Stereoselectivity
Chemistry
Inorganic chemistry

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