Exploration of cobalt@N-doped carbon nanocomposites toward hydrogen peroxide (H2O2) electrosynthesis: A two level investigation through the RRDE analysis and a polymer-based electrolyzer implementation

Abstract The Oxygen Reduction Reaction (ORR) catalyzed by N-carbon electrocatalyst was investigated, focusing on the fundamental features for the selective H2O2 formation. The electrochemical characterization was primarily performed by the use of the Rotating Ring Disc Electrode (RRDE) tool in both hydrodynamic Linear Sweep Voltammetry (LSV) mode and by Chronoamperometry (CA) measurement. We rationalized the structure/activity relationship, reaching a new state-of-the-art in terms of current density for the H2O2 generation. The study also explored the performance in relation with the electrode deposit procedure that is of fundamental importance to achieve a suitable macroscopic electrode preparation. Furthermore, the electrode implementation in a polymer membrane static flow electrolyzer setup, was evaluated to understand how the material catalytic features such as current ranges and selectivity scale up from a classical three electrode system to a more realistic application-focused environment.