Fluorination of α,β-unsaturated carbonyl compounds using elemental fluorine
2016
Abstract Elemental fluorine was successfully added across the double bond of various α,β-unsaturated carbonyl compounds. A necessary ingredient is a presence of alcohol in the solvent mixture. Unlike all other halogen's addition to olefins, fluorine adds itself in a syn mode specificity. The vic difluoro products were easily dehydrofluorinated to form the corresponding α-fluoro carbonyl derivatives.
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