Transition‐Metal‐Free BF3‐Mediated Oxidative and Non‐oxidative Cross‐Coupling of Pyridines.
2015
Treatment of various pyridine substrates bearing substituents at positions 2, 3, or 4 with alkynyllithium reagents under sequential conditions A), B), C) causes substitution at C-2 or C-6 to afford highly functionalized derivatives.
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