Development of New Ni-Al Porous Alloys for Metal-Supported Solid Oxide Fuel Cells
2014
The technique of synthesis of Ni-16mass%Al open cell type porous intermetallic materials that can be treated in inert or regenerative atmospheres at temperature up to 1600 K without changing their functional properties has been developed. Materials with Ni 3Al-NiAl phase composition, porosity of 42 %, sizes of transport pores up to 10 µm, sizes of core elements equal to 40 µm, and specific surface of open porosity of 90 mm -1 have been produced. It is demonstrated that after complete oxidation of the given materials, the NiO-NiAl 2O4 composite is formed, whose reduction in hydrogen flux results in the formation of Ni-NiAl 2O4 cermet; the shape of the porous material in the course of oxidation/reduction does not change.
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