Ball milling synthesis method of mercaptothiazole type metal compounds

The invention discloses a ball milling synthesis method of mercaptothiazole type metal compounds as shown in formula (I) and formula (II). The method comprises the steps of adding 2-amino-5-mercapto-1, 3, 4-thiadiazole or 2-mercaptobenzothiazole into a ball milling reactor, further adding a ball body, a metal salt and a solvent to perform ball milling reaction, performing TLC (tracking level control) monitoring, performing post-treatment on a reaction mixture after the end of reaction, adding 2-amino-5-mercapto-1, 3, 4-thiadiazole to obtain the compounds as shown in the formula (I), and adding 2-mercaptobenzothiazole to obtain the compounds as shown in the formula (II). The synthesis method of the mercaptothiazole type metal compounds, provided by the invention, has the advantages of simple process, effect of basically eliminating three wastes and high yield, and is suitable for industrial applications.