An Effective Kinetic Resolution of Racemic α-Arylpropanoic Acids, α-Arylbutanoic Acids, and β-Substituted-α-arylpropanoic Acids with Bis(9-phenanthryl)methanol as a New Achiral Nucleophile in the Asymmetric Esterification Using Carbox

Kenya Nakata,Yu-suke Onda,Keisuke Ono,Isamu Shiina

An Effective Kinetic Resolution of Racemic α-Arylpropanoic Acids, α-Arylbutanoic Acids, and β-Substituted-α-arylpropanoic Acids with Bis(9-phenanthryl)methanol as a New Achiral Nucleophile in the Asymmetric Esterification Using Carbox

2011

Kenya Nakata
Yu-suke Onda
Keisuke Ono
Isamu Shiina

A widely applicable method is developed via generation of mixed anhydrides followed by reaction with bis(9-phenanthryl)methanol in the presence of (+)-benzotetramisole as the catalyst.

Keywords:

Methanol
Organic chemistry
Nucleophile
Inorganic chemistry
Kinetic resolution
Chemistry
Chirality (chemistry)
Catalysis

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