{2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ2N,N′}(η3-prop-2-enyl)palladium(II) hexafluorophosphate
2014
The title compound, [Pd(C3H5)(C17H15N3S2)]PF6, is built up by a [(η3-allyl)Pd]2+ fragment coordinated by a 2,6-bis[(pyridin-2-yl)sulfanylmethyl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) A]. The PdII atom is tetracoordinated in a strongly distorted square-planar environment mainly determined by the η3-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes.
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