Corona-resistance polyimide film and manufacturing method thereof

2011 
The invention discloses a corona-resistance polyimide film, which comprises emulsion, amine solution and pyromellitic dianhydride, wherein the emulsion comprises 7 to 14 mass percent of nano metal oxide and nano metal nitride, 0.3 to 0.6 mass percent of dispersant, 0.3 to 0.5 mass percent of emulsifier and the balance of pyrrolidone; the amine solution comprises 20 to 25 mass percent of 4,4'-diamino-diphenyl ether and 75 to 80 mass percent of dimethylacetylamide, and the mass ratio of the emulsion to the amine solution is 1:(1.1-1.3); and the mass ratio of the pyromellitic dianhydride to the 4,4'-diamino-diphenyl ether is 1:(1.09). The invention also discloses the manufacturing method of the corona-resistance polyimide film. In the invention, the nano metal oxide and nitride are fully dispersed in polyamic acid resin by adding the emulsifier and dispersant and by a high-pressure emulsification technique, and the content of the nano metal oxide and nitride in the polyamic acid resin is high. Therefore, the produced film has high corona resistance and small astigmatic aberration, and at the same time, the film has high mechanical performance, electrical performance and the like.
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