The reactivity of spinach plastocyanin mutants with inorganic oxidants [Fe(CN)6]3– and [Co(phen)3]3+

Panayotis Kyritsis,Lennart G. Lundberg,Margareta Nordling,Tore Vänngård,Simon Young,Nicholas P. Tomkinson,A. Geoffrey Sykes

The reactivity of spinach plastocyanin mutants with inorganic oxidants [Fe(CN)6]3– and [Co(phen)3]3+

1991

Panayotis Kyritsis
Lennart G. Lundberg
Margareta Nordling
Tore Vänngård
Simon Young
Nicholas P. Tomkinson
A. Geoffrey Sykes

Stopped-flow rate constants for the oxidation of spinach plastocyanin PCuI mutants Leu12Glu, Leu12Asn, Asp42Asn and Tyr83Phe have been determined, and are discussed in terms of two-site reactivity for electron transfer.

Keywords:

Inorganic chemistry
Chemistry
Reaction rate constant
Plastocyanin
Spinach
Electron transfer
Mutant
Chenopodiaceae
Plastocyanine

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