Sugar–Poly(para‐phenylene ethynylene) Conjugates as Sensory Materials: Efficient Quenching by Hg2+ and Pb2+ Ions

Three polar poly(para-phenylene ethynylene)s (PPE) were synthesized by utilizing the Heck-Sonogashira protocol. Two of the PPEs carry β-glucopyranose substituents. Depending upon the linker used between the glycol units and the backbone, the fluorescence of these PPEs can he quenched by Hg 2 + and Ph 2 + to a varying degree. Monomeric model compounds that are substituted with only one glucose unit are not efficiently quenched. The presence of many glucose substituents in one PPE assembly led to a large increase in the binding constant to Hg 2 + and quenching of the fluorescence was amplified.