Parallel-plate fracture transport experiments of nanoparticulate illite in the ultra-trace concentration range investigated by Laser-Induced Breakdown Detection (LIBD)

Abstract This study investigates the appropriateness of monodisperse carboxylated polystyrene spheres as clay colloid analogues. Colloid transport experiments using Na-illite are conducted within a parallel-plate fracture flow cell with an aperture of 0.75 mm at pH 5 under low ionic strength (1 mM NaCl) and laminar flow (7 mL/h) conditions. The effects of collector surface material (Grimsel granodiorite or acrylic glass), fracture orientation and residence time on colloid retention are examined. In order to avoid full surface coverage effects, ultra-trace (30 ppb) Na-illite colloid concentrations are used. Laser-induced breakdown detection is applied in order to detect and quantify the Na-illite colloids. The results are directly compared to the experiments of Stoll, et al. [1] who investigated the transport and surface interaction of carboxylated polystyrene spheres (25 and 1000 nm diameter) using the same experimental setup and conditions. It is concluded that polystyrene spheres are no ideal analogue to predict the mobility and transport behavior of a polydisperse clay colloid suspension. Despite the higher solid density, the Na-illite colloids show higher mobility compared to the polystyrene spheres without significant impact of surface roughness or gravity. The platelet shape, the non-uniform surface charge distribution and slower sedimentation may account for the observed differences.