catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]
2008
In the title compound, {[Co(C10H8N2)(H2O)4](ClO4)2·2C10H8N2·2H2O}n, slightly distorted octahedrally coordinated CoII ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supramolecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water molecules. A twofold interpenetrated primitive cubic supramolecular network is formed by the interaction of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4′-bipyridine molecules.
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