In situ fabrication of nitrogen doped graphitic carbon networks coating for high-performance extraction of pyrethroid pesticides

Abstract The tailor-prepare solid phase microextraction (SPME) coatings with stable and excellent properties to effectively extract analytes from sample matrix still remains a challenge. Herein, a nitrogen doped graphitic carbon networks (NG-CNTW) coated fiber was fabricated by direct carbonization of nanosized ZIF-67 crystals (nano-ZIF-67) that grown on stainless steel wire. The NG-CNTW coated fiber coupled with gas chromatography-tandem mass spectrometry (GC-MS/MS) was applied for enrichment and determination of pyrethroids. The NG-CNTW coating exhibited high surface area and hierarchical porous structures that facilitate diffusion and accessibility of target molecules. Simultaneously, the nitrogen doped and highly graphitic structures endow the coating with high adsorption affinity for aromatic compounds. Under optimum conditions, the SPME-GC-MS/MS method presented wide range of linearity performance (0.08–200.0 ng g−1), low limits of detection (0.02–0.5 ng g−1) and good repeatability (RSD