Retro-Mannich Reactions of 3-Alkyl-3,4-dihydro-2H-1,3-benz[e]oxazines and the Synthesis of Axially Chiral Resorcinarenes.
2003
Abstract Intermediates involved in the conversion of 3-alkyl-3,4-dihydro-2H-1,3-benz[e]oxazines into 2-N,N-dialkylaminomethylphenol derivatives, using morpholine and other high boiling secondary amines, have been identified and characterised. Additional experiments have established the involvement of o-quinone methide intermediates in the retro-Mannich reactions. Axially chiral resorcinarenes have been prepared by utilising the exchange reactions.
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