Free-amine directed arylation of biaryl-2-amines with aryl iodides by palladium catalysis.

Zunjun Liang,Ruokun Feng,Hong Yin,Yuhong Zhang

Free-amine directed arylation of biaryl-2-amines with aryl iodides by palladium catalysis.

2013

Zunjun Liang
Ruokun Feng
Hong Yin
Yuhong Zhang

A new palladium-catalyzed free-amine directed arylation of C(sp2)–H bonds in the presence of AgOAc and TFA is described. Biaryl-2-amines react with various aryl iodides to give the corresponding mono- or diarylated products with exclusive regioselectivity.

Keywords:

Photochemistry
Aryl
Regioselectivity
Catalysis
Palladium
Inorganic chemistry
Amine gas treating
Chemistry
Organic chemistry

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