Study of the thermal property of copper oxide nanowires
2009
As a high potential candidate for field-emission emitters, gas sensors, high-critical temperature superconductors, copper
oxide NWs have been intensively studied in the synthesized methods, electrical properties and chemical properties.
However, there are not many literatures report on the thermal property of them. It is important for one to understand the
thermal behavior in order to justify the failure limit of the material especially in nanoscale. In this paper, copper oxide
NWs synthesized through direct heating in atmospheric ambient were rapidly annealed in nitrogen ambient at different
temperature to check the critical thermal failure point where the free standing copper oxide NWs start to collapse. It was
found that copper oxide NWs with diameters around 100 nm started to collapse after 30 minutes of annealing in the
nitrogen ambient at 300°C due to the thermal shock incurred by rapid annealing. Increase in temperature will cause the
NWs with bigger diameters start to fail. NWs in same diameter range will be able to withstand the temperature up to
several hours if no thermal shock is induced. This was happening even when the wires were heated in a higher
temperature of 600°C. This result is important for copper oxide NWs when they are incorporated into the other heat
sensitive device. The results are important for justifying the failure behavior for devices based on copper oxide NWs.
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