A high spin molecular square based on square pyramidal CoII and tetrahedral MnII centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]

Ferdi Karadas,Eric J. Schelter,Andrey V. Prosvirin,John Bacsa,Kim R. Dunbar

A high spin molecular square based on square pyramidal CoII and tetrahedral MnII centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]

2005

Ferdi Karadas
Eric J. Schelter
Andrey V. Prosvirin
John Bacsa
Kim R. Dunbar

A high spin molecular square of square pyramidal CoII and tetrahedral MnII corners exhibiting an overall S = 4 ground state has been crystallized and its magnetic properties investigated.

Keywords:

Ground state
Square pyramidal molecular geometry
Photochemistry
Spin-½
Inorganic chemistry
Triphos
Tetrahedron
Chemistry
Nuclear magnetic resonance
Crystallography

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