.eta.2-Acyl coordination and .beta.-carbon-hydrogen bond interaction in acyl complexes of molybdenum. Crystal and molecular structures of tris(trimethylphosphine)carbonylchloro(.eta.2-trimethylsilylacetyl)molybdenum [Mo(.eta.2-COCH2SiMe3)Cl(CO)(PMe3)3] and the cyclic complex [cyclic] Mo(COCH3)(S2CNMe2)(CO)(PMe3)2

Ernesto Carmona,Luis Sánchez,Jose M. Marin,Manuel L. Poveda,Jerry L. Atwood,Ralph D. Priester,Robin D. Rogers

.eta.2-Acyl coordination and .beta.-carbon-hydrogen bond interaction in acyl complexes of molybdenum. Crystal and molecular structures of tris(trimethylphosphine)carbonylchloro(.eta.2-trimethylsilylacetyl)molybdenum [Mo(.eta.2-COCH2SiMe3)Cl(CO)(PMe3)3] and the cyclic complex [cyclic] Mo(COCH3)(S2CNMe2)(CO)(PMe3)2

1984

Ernesto Carmona
Luis Sánchez
Jose M. Marin
Manuel L. Poveda
Jerry L. Atwood
Ralph D. Priester
Robin D. Rogers

Le premier complexe cristallise dans P2 1 2 1 2 1 avec Z=4; affinement jusqu'a R=0,025. Le second cristallise dans P2 1 /c avec Z=4; affinement jusqu'a R=0,029

Keywords:

Carbon–hydrogen bond activation
Molybdenum
Hydrogen bond
Trimethylphosphine
Molecule
Tris
Denticity
Organic chemistry
Inorganic chemistry
Chemistry
Ligand
Crystal structure
Inorganic compound

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