Síntesis, caracterización e hidroformilación catalítica de 1-hexeno con nuevos sistemas híbridos: (Co2(CO)8) y (Co2(CO)6(PPh3)2) sobre SiO2 funcionalizada Synthesis, characterization and 1-hexene catalytic hydroformylation with new hybrid systems: (Co 2 (CO) 8 ) and (Co2(CO)6(PPh3)2) on functionalized SiO2
2013
In this paper we present the synthesis of new hybrid systems [Co2(CO)8] and [Co2(CO)6(PPh3)2] supported on SiO2, functionalized with 3-2(aminoethylamino)]trimethoxysilane and passivated with triethoxymethylsilane, using the post-synthesis method. The solids were characterized using FT-IR, EDX-SEM, N2 adsorption, ICP-AES, MS and TGA. 1-hexene catalytic hydroformylation with the new hybrid systems was tried.
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