Key Role of d0 and d10 Cations for the Design of Semiconducting Colusites: Large Thermoelectric ZT in Cu26Ti2Sb6S32 Compounds

Takashi Hagiwara,Koichiro Suekuni,Pierric Lemoine,Andrew Supka,Raju Chetty,Emmanuel Guilmeau,Bernard Raveau,Marco Fornari,Michihiro Ohta,Rabih Al Rahal Al Orabi,Hikaru Saito,Katsuaki Hashikuni,Michitaka Ohtaki

Key Role of d0 and d10 Cations for the Design of Semiconducting Colusites: Large Thermoelectric ZT in Cu26Ti2Sb6S32 Compounds

2021

Takashi Hagiwara
Koichiro Suekuni
Pierric Lemoine
Andrew Supka
Raju Chetty
Emmanuel Guilmeau
Bernard Raveau
Marco Fornari
Michihiro Ohta
Rabih Al Rahal Al Orabi
Hikaru Saito
Katsuaki Hashikuni
Michitaka Ohtaki

Cu–S-based materials with sphalerite-derivative structures are of interest for their complex cationic distribution, rich crystal structure chemistry, and potential in energy conversion and optoelec...

Keywords:

Chemical physics
Key (cryptography)
Crystal structure
Cationic polymerization
Energy transformation
Materials science
Thermoelectric effect

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