Hysteretic spin crossover in isomeric iron(II) complexes

Mark B. Bushuev,Viktor P. Krivopalov,Elena B. Nikolaenkova,Katerina A. Vinogradova,Yuri V. Gatilov

Hysteretic spin crossover in isomeric iron(II) complexes

2018

Mark B. Bushuev
Viktor P. Krivopalov
Elena B. Nikolaenkova
Katerina A. Vinogradova
Yuri V. Gatilov

Two mononuclear iron(II) complexes with isomeric N,N,N-tridentate pyrimidine-based ligands were synthesized. Both complexes show reproducible hysteretic spin crossover. Low spin state to high spin state switching is cooperative due to autocatalysis.

Keywords:

Photochemistry
Pyrimidine
Inorganic chemistry
Chemistry
Autocatalysis
Spin crossover
Spin states
Ligand
Hysteresis
Crystallography

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