Functional poly(1,4-ketone)s with pendant hydroxy moieties, 1. Pd(II)-catalyzed alternating copolymerization of carbon monoxide and allylbenzene derivatives
2000
Functional poly(1,4-ketone)s were prepared by alternating copolymerization of carbon monoxide with substituted allylbenzenes, namely 2-allylphenol 1. 2-allyl-4-methylphenol 2. 2-allyl-6-methylphenol 3. 2-allylmethoxybenzene 4. 2-allylethoxybenzene 7. The dicationic Pd(II) bis(phosphine) complex [Pd(DPPP)(CH 3 CN) 2 ] (BF 4 ) 2 10 [DDP = 1,3-bis-diphenylphosphino)propane] was used as the catalyst precursor. Optimum results occurred with monomers that bear oxygen-containing substituents located in ortho-position to the allyl group. Copolymers derived from henolic monomers structurally differ from their protected analogues because they predominantly display ketalic character due to nucleophilic attack of the OH groups towards neighbored keto moieties. Pendant hydroxy moieties of functional poly (1,4-ketone)s were reacted ith chlorides and anhydrides of carboxylic acids to form the corresponding esters as a model reaction for grafting processes. Furthermore, isocyanates were used in terms of post-polymerization functionalization. Graph. Dependence of molecular weight and copolymer yield on the acivator concentration in the alternating copolymerization of CO and 1.
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