Diffraction and Spectroscopic Studies of the Cobaltic Acid System HCoC2–DCoO2

Cobaltic acid, HCoO2, and deuterated cobaltic acid, DCoO2, have been prepared and studied by x‐ray and neutron‐diffraction techniques, and by infrared spectroscopy and cold‐neutron scattering. The materials crystallize in apparent space group D3d5–R<3¯m of the trigonal system with three molecules in a hexagonal cell of dimensions: HCoO2, a = 2.851(1), c = 13.150(5) A; DCoO2, a = 2.854(1), c = 13.354(5) A. The O–O distance, as determined by neutron‐powder studies, of HCoCO2 is 2.50(2) A. On this basis and the fact that there are three O–H–O bonds along the c direction, the O–D–O distance is 2.57(2) A. Hence, the isotope effect here is as large as in the system HCrO2–DCrO2. Infrared studies at room temperature and at − 195°C over the region 70–4000 cm−1 may be interpreted in terms of an effectively symmetric O–H–O bond and an effectively asymmetric O–D–O bond. Although the neutron inelastic scattering measurements are not inconsistent with this interpretation, there is a band centered at 264 cm−1 in the neu...