Ether-free polymeric anion exchange materials with extremely low vanadium ion permeability and outstanding cell performance for vanadium redox flow battery (VRFB) application

Abstract Ether-free poly( p -phenylene)-based anion exchange membrane materials with outstanding vanadium ion blocking properties are reported. The synthesized ionomers with a rigid backbone structure show small dimensional variations despite the high ion exchange capacities. Among the synthesized membranes, the QPPP-2 membrane with ion exchange capacity of 2.1 meq·g −1 exhibits high anion (OH − , SO 4 2− , and Cl − ) conductivity. The QPPP-2 membrane shows an extremely low diffusion coefficient (2.12 × 10 −9  cm 2  min −1 ) for VO 2+ , which is much lower than that of Nafion 115 (2.88 × 10 −6  cm 2  min −1 ), indicating the vanadium ion blocking property of QPPP-2. Moreover, the chemical and operational stabilities of the membranes are investigated via ex situ soaking tests in 0.1 M VO 2 + solution and in situ operation tests for 100 cycles, respectively. The vanadium redox flow battery single cell assembled with the QPPP-2 membrane exhibits a coulombic efficiency of 99%, voltage efficiency of 87%, and energy efficiency of 86% during 100 cycles at 80 mA cm −2 . The excellent chemical, morphological, and electrochemical properties of the QPPP-2 membrane make it suitable for use in vanadium redox flow battery.