Successive Protonation and Methylation of Bridging Imido and Nitrido Ligands at Titanium Complexes.

The reactions of nitrido complexes [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] (1) and [{Ti(η5-C5Me5)}4(μ3-N)4] (2) with electrophilic reagents ROTf (R = H, Me; OTf = OSO2CF3) in different molar ratios have allo...